Description
Soap is generally a sodium salt of fatty acids. The importance of common salt to animal nutrition has been recognized since prehistoric times. The most common compound is sodium chloride, (table salt).Sodium is a Group 1 element (or IA in older labelling styles). Group 1 elements are often referred to as the "alkali metals". The chemistry of sodium is dominated by the +1 ion Na+.
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General information
Discoveror: Sir Humphrey Davy
Date discovered: 1807
Discovered at: England
Meaning of name: From the English word "soda" (the origin of the symbol Na comes from the Latin word "natrium")
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Physical data
Standard state: solid at 298 K
Colour: silvery white/
Density of solid at ambient temperature/kg m-3: 968
Molar volume/cm3: 23.78
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Radii /pm
Atomic: 190
Covalent (single bond):
Pauling radius for the ion [Na]-: no data
Valence shell orbital radius maxima (Rmax)
| orbital |
s |
p |
d |
f |
| radius | 179.4 | no data | no data | no data |
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Electronegativities
Both values are quoted on the Pauling scale.
Pauling: 0.93
Allred Rochow: 1.01
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Crystal Structure
structure: bcc (body-centred cubic)
The following CrystalMaker image represents the solid state structure. For most elements, the most stable allotrope is illustrated. Try WebElements version 2 for interactive virtual reality and CHIME images.
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Temperatures (/K)
melting point: 370.87
boiling point: 1156
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Enthalpies /kJ mol-1
fusion: 2.60
vaporization: 97.7
single bond enthalpies:
| Na-F |
Na-Cl |
Na-Br |
Na-I |
Na-Na |
| 477 |
408 |
363 |
304 |
73.60 |
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Ionization enthalpies /kJ mol-1
| Number |
Enthalpy |
| 1st | 495.8 |
| 2nd | 4562.4 |
| 3rd | 6912 |
| 4th | 9544 |
| 5th | 13353 |
| 6th | 16610 |
| 7th | 20115 |
| 8th | 25490 |
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Isotopes
This section gives some data for naturally occurring isotopes.
| Nominal mass |
Accurate mass |
% natural abundance |
| 23Na | 22.9897677 (10) | 100 |
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Further Information
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